AlmaRegulus,Yes – the person who's Valentine conjuncts my Ascendant exact is actually the founder of my company / my "boss", yet we are only a few years apart and have really great rapport, and basically function as friends. We flirt.
I always wondered how he might feel about me, especially with his the Valentine conjunct my Ascendant exactly.
His Mars also conjuncts my Ascendant, but falls in my 12th house, not my 1st house. So I don't know if this means that there is some hidden attraction?