A Libra Asc with Leo Sun, nice! Are you incredibly gorgeous or what! You also have Mars in the 1st though a bit far from the ascendant to call it a conj. Mars doesn't like being in Libra. Are you always trying to make things work with people even if your Leo Sun wants to just walk away and call it a day? If you can manage this right, and in a balanced manner, you may be very successful socially and fit for leadership positions.
Venus in the 9th likes to travel to far-away places and get to know people from different cultures. Gemini rules your 9th so expect your communication/media/linguistic interests to take you places!
You like a man who is getting well with everyone no matter what. Social and mental/intellectual activity and vigor are very important to your choice of mate.
You have most of your personal planets in air signs (only Sun is in fire), and only Jup and Sat are in earth. Even your NN is in fire (Leo). The air element is your comfort zone and one you need to get out of as your soul evolves towards your NN goal. Your Aqua Moon opposes your NN. You need to lead by your Leo Sun rather than by your Aqua Moon. Use your air sign talents (friendliness, intellectual talents, an open and broad mind) to achieve your Leo NN goal of being passionate about what you believe, being generous and more "hands-on" with people, loyal to a few rather than to all, and proud to be YOU versus part of the Universe.
Hope some of this resonates.